Influence of pre-oxidation on the hot corrosion of Ti3SiC2 in the mixture of Na2SO4-NaCl melts

Polycrystalline Ti₃SiC₂ suffered from serious hot corrosion attack in the mixture of 75wt.%Na₂SO₄ + 25wt.%NaCl melts at 850 °C. In order to improve the hot corrosion resistance of this material, pre-oxidation treatment was conducted at 1200 °C in air for 2 h. A duplex oxide scale with an outer layer of TiO₂ and an inner layer of a mixture of TiO₂ and SiO₂ was formed during the pre-oxidation. Because the outer oxide layer of the pre-oxidation treated specimens could inhibit hot corrosion process, they exhibited good hot corrosion resistance in the mixture of 75wt.%Na₂SO₄ + 25wt.%NaCl melts at 850 °C for 50 h. However, during the hot corrosion the outer layer of TiO₂ would degrade gradually. Once the outer layer damaged, the hot corrosion rate increased sharply, the corrosion behavior was similar to Ti₃SiC₂ corroded under the same conditions. The microstructure and phase compositions of the hot corrosion samples were investigated by SEM/EDS and XRD.     

Stability of protective oxide films in waste incineration environment—solubility measurement of oxides in molten chlorides

Solubility measurements of several oxides in molten NaCl-KCl and NaCl-KCl-Na₂SO₄-K₂SO₄ were conducted in three different levels of basicity. The dissolution behavior of the oxides showed almost the same tendency as that shown by the dissolution behavior of the oxides in molten Na₂SO₄ in literature. In a waste incineration environment, a protective Cr₂O₃ film easily dissolves in molten chlorides as CrO₄²⁻ because pO²⁻ of the molten chlorides tends to have a small value due to the effect of water vapor contained in the combustion gas. From the result of the solubility measurement, the addition of molybdenum and/or silicon was expected to improve the corrosion resistance of alloys. Laboratory corrosion tests confirmed this expectation. However, the scale analysis suggested that the effect of molybdenum could not be explained completely by only the mechanism derived from the result of the solubility measurement.     

预应力钢丝用盘条在斯太尔摩控制冷却线的生产实践

介绍高强度、大直径、低松弛预应力钢丝用高碳钢盘条在标准型斯太尔摩控制冷却线的生产实践。内容包括作业线概况、原料准备、工艺制度及实际结果和分析。     

埋地钢管热缩套补口材料现场应用状况调查与分析

通过对埋地钢管热缩套补口材料的现场应用状况的调查,分析了腐蚀发生的原因,探讨了改进钢管热缩套补口施工工艺和优化补口结构的方法.     

Effects of annealing at high pressure on structure and mechanical properties of Al87Ni7Gd6 metallic glass

The effects of annealing and annealing with a superimposed pressure of 940 MPa on the primary crystallization behaviour of α-Al and the resulting micro-hardness have been studied for as-quenched Al₈₇Ni₇Gd₆ metallic glass. Isothermal annealing experiments were conducted for 30 min at 188 °C, 191 °C, and 205 °C in silicone oil maintained either at atmospheric pressure (i.e. 0.1 MPa) or at 940 MPa. XRD analyses detected the evolution of structure with annealing at 0.1 MPa, while specimens annealed with 940 MPa pressure exhibited sharper diffraction peaks than those annealed at 0.1 MPa. DSC measurements were conducted on the as-received amorphous ribbons as well as ribbons annealed at different temperatures at either 0.1. MPa or with 940 MPa superimposed pressure. Specimens annealed with 940 MPa pressure exhibited higher onset temperatures (i.e. T_x1) and temperatures for the first exothermic peak (i.e. T_p1) for primary crystallization. TEM measurements revealed an increase in the volume fraction of α-Al with increases in annealing temperature, while micro-hardness measurements revealed an increase in hardness with increasing amounts of α-Al. Specimens annealed with 940 MPa pressure exhibited further increases in both the volume fraction of α-Al and resulting micro-hardness.     

非调质钢的合金设计与热加工工艺及性能

论述了非调质钢的性能特点，分析了V、Nb、Ti、Mn、Cr、Si等常用合金元素对非调质钢组织和力学性能的影响，并对热加工工艺、热处理等因素个性能的影响作了分析和讨论。     

堆焊技术在板带热连轧机支承辊上的应用

本文介绍堆焊技术在热连轧机支承辊再利用方面的试验和应用,叙述了堆焊材料的选择,堆焊工艺以及取得的效果和经济效益。     

B 炸药中绝热剪切带形成机理的细观研究

通过对快速加载后Ｃｏｍｐ．药柱剖面的扫描电镜和光学显微镜观察分析，对Ｃｏｍｐ．Ｂ炸药在快速加载下剪切带形成机理的微观机制有了初步的认识。文中采用形变试样的剖面观察分析方法，针对固体药柱这种比较软的材料，如何进行磨样、抛光、浸蚀，作了一些尝试和探索，总结出一套有效的实施办法。对不同加载速率条件下受压缩的药柱中细观组织进行了观察、分析、比较，首次给出国产Ｃｏｍｐ．Ｂ炸药装药的原始细观组织形貌，以及快速加载后药柱中细观组织形貌。经过分析，得到冲击载荷下炸药装药中绝热剪切带形成、发展的定性认识，为分析Ｃｏｍｐ．Ｂ炸药装药受冲击载荷时热点形成机理提供了一些有益的实验依据。     

Artificial neural network application for modeling the rail rolling process

Rail rolling process is one of the most complicated hot rolling processes. Evaluating the effects of parametric values on this complex process is only possible through modeling. In this study, the production parameters of different types of rails in the rail rolling processes were modeled with an artificial neural network (ANN), and it was aimed to obtain optimum parameter values for a different type of rail. For this purpose, the data from the Rail and Profile Rolling Mill in Kardemir Iron & Steel Works Co. (Karabük, Turkey) were used. BD1, BD2, and Tandem are three main parts of the rolling mill, and in order to obtain the force values of the 49 kg/m rail in each pass for the BD1 and BD2 sections, the force and torque values for the Tandem section, parameter values of 60, 54, 46, and 33 kg/m type rails were used. Comparing the results obtained from the ANN model and the actual field data demonstrated that force and torque values were obtained with acceptable error rates. The results of the present study demonstrated that ANN is an effective and reliable method to acquire data required for producing a new rail, and concerning the rail production process, it provides a productive way for accurate and fast decision making.     

Cu2O-CuAlO2-Cu基金属陶瓷导电性能研究

通过热压技术制备Cu2O-10CuAlO2-xCu金属陶瓷材料，并对其导电性能进行了研究。结果表明，Cu2O-10CuAlO2-xCu在Cu含量超过15wt．％后呈金属导电性。材料的微观结构观察及物理性能测试表明，金属陶瓷材料的电导率不仅取决于材料的金属相含量，还取决于金属相颗粒尺寸和孔隙率的大小。材料中金属相的颗粒尺寸取决于热压工艺参数，随着热压温度的升高而增大，但随热压压力的升高而减小。